In this paper, the Chebychev Spectral collocation method is applied for the thermal analysis ofconvective-radiative straight fins with the temperature-dependent thermal conductivity. The developed heat transfermodel was used to analyse the thermal performance, establish the optimum thermal design parameters, and also, investigate the effects of thermo-geometric parameters and thermal conductivity (nonlinear) parameters on thethermal performance of the fin. The results of this study reveal that the rate of heat transfer from the fin increases asthe convective, radioactive, and magnetic parameters increase. This study establishes good agreement between theobtained results using Chebychev Spectral collocation method and the results obtained using Runge-Kutta methodalong with shooting, homotopy perturbation, and adomian decomposition methods.